Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide.
Identifieur interne : 000785 ( Main/Exploration ); précédent : 000784; suivant : 000786Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide.
Auteurs : RBID : pubmed:24192808Abstract
Dinuclear complexes of aluminum and indium with a bis(phenoxy-imine) platform have been synthesized and used in the polymerization of lactide. Kinetic studies demonstrate that the dialuminum precursor provides a more favorable reaction pathway in terms of activation free energy than that of directly related monoaluminum systems. No similar trend is observed with the corresponding diindium-monoindium systems, which is attributed to a dissimilar ROP mechanism.
DOI: 10.1039/c3cc47572g
PubMed: 24192808
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide.</title><author><name sortKey="Normand, M" uniqKey="Normand M">M Normand</name><affiliation wicri:level="3"><nlm:affiliation>Institut des Sciences Chimiques de Rennes, Organometallics: Materials and Catalysis Laboratories, UMR 6226 CNRS-Université de Rennes 1, F-35042 Rennes Cedex, France. evgueni.kirillov@univ-rennes1.fr jean-francois.carpentier@univ-rennes1.fr.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Institut des Sciences Chimiques de Rennes, Organometallics: Materials and Catalysis Laboratories, UMR 6226 CNRS-Université de Rennes 1, F-35042 Rennes Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Roisnel, T" uniqKey="Roisnel T">T Roisnel</name></author><author><name sortKey="Carpentier, J F" uniqKey="Carpentier J">J-F Carpentier</name></author><author><name sortKey="Kirillov, E" uniqKey="Kirillov E">E Kirillov</name></author></titleStmt><publicationStmt><date when="2013">2013</date><idno type="doi">10.1039/c3cc47572g</idno><idno type="RBID">pubmed:24192808</idno><idno type="pmid">24192808</idno><idno type="wicri:Area/Main/Corpus">000330</idno><idno type="wicri:Area/Main/Curation">000330</idno><idno type="wicri:Area/Main/Exploration">000785</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Dinuclear complexes of aluminum and indium with a bis(phenoxy-imine) platform have been synthesized and used in the polymerization of lactide. Kinetic studies demonstrate that the dialuminum precursor provides a more favorable reaction pathway in terms of activation free energy than that of directly related monoaluminum systems. No similar trend is observed with the corresponding diindium-monoindium systems, which is attributed to a dissimilar ROP mechanism.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="In-Process"><PMID Version="1">24192808</PMID><DateCreated><Year>2013</Year><Month>11</Month><Day>19</Day></DateCreated><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1364-548X</ISSN><JournalIssue CitedMedium="Internet"><Volume>49</Volume><Issue>99</Issue><PubDate><Year>2013</Year><Month>Dec</Month><Day>25</Day></PubDate></JournalIssue><Title>Chemical communications (Cambridge, England)</Title><ISOAbbreviation>Chem. Commun. (Camb.)</ISOAbbreviation></Journal><ArticleTitle>Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide.</ArticleTitle><Pagination><MedlinePgn>11692-4</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c3cc47572g</ELocationID><Abstract><AbstractText>Dinuclear complexes of aluminum and indium with a bis(phenoxy-imine) platform have been synthesized and used in the polymerization of lactide. Kinetic studies demonstrate that the dialuminum precursor provides a more favorable reaction pathway in terms of activation free energy than that of directly related monoaluminum systems. No similar trend is observed with the corresponding diindium-monoindium systems, which is attributed to a dissimilar ROP mechanism.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Normand</LastName><ForeName>M</ForeName><Initials>M</Initials><Affiliation>Institut des Sciences Chimiques de Rennes, Organometallics: Materials and Catalysis Laboratories, UMR 6226 CNRS-Université de Rennes 1, F-35042 Rennes Cedex, France. evgueni.kirillov@univ-rennes1.fr jean-francois.carpentier@univ-rennes1.fr.</Affiliation></Author><Author ValidYN="Y"><LastName>Roisnel</LastName><ForeName>T</ForeName><Initials>T</Initials></Author><Author ValidYN="Y"><LastName>Carpentier</LastName><ForeName>J-F</ForeName><Initials>JF</Initials></Author><Author ValidYN="Y"><LastName>Kirillov</LastName><ForeName>E</ForeName><Initials>E</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Chem Commun (Camb)</MedlineTA><NlmUniqueID>9610838</NlmUniqueID><ISSNLinking>1359-7345</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>11</Month><Day>7</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>11</Month><Day>7</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>11</Month><Day>7</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1039/c3cc47572g</ArticleId><ArticleId IdType="pubmed">24192808</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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